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Atom

From Natural Philosophy Wiki

An atom is the smallest unit of a chemical element that retains that element's identity: a dense positively charged Nucleus surrounded by electrons.

The standard account

The modern picture was assembled in about thirty years. J. J. Thomson identified the electron in 1897. Rutherford's alpha-scattering experiments, reported in 1911, showed that the positive charge and nearly all the mass are concentrated in a nucleus some hundred thousand times smaller than the atom itself — an atom is roughly 10−10 m across, a nucleus roughly 10−15 m. Bohr's 1913 model quantised the electron's angular momentum and reproduced the Hydrogen Atom spectrum, but it was an admitted hybrid: it forbade by fiat the radiation that classical Electrodynamics demands of an accelerating charge. The wave mechanics of de Broglie, Schrödinger and Heisenberg replaced the orbits with stationary states in 1925–1926, and Pauli's exclusion principle explained why electrons stack into shells and hence why the periodic table has the structure it does.

The quantum-mechanical account is quantitatively extraordinary: atomic transition frequencies are predicted and measured to more than ten significant figures, and atomic clocks built on them define the second. What it does not supply is a picture — the electron in a stationary state is described by a probability amplitude, not a trajectory — and that absence is the starting point for most of the alternatives catalogued on this wiki.

On this wiki

Category:Atomic Structure holds around sixty pages of alternative models, most of them attempts to restore a definite physical structure to the atom.

These models differ from each other at least as much as they differ from quantum mechanics, and few of them attempt the spectroscopic precision that is the standard theory's principal achievement. Readers evaluating them should ask specifically what each predicts numerically.

See also